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ferrites processed by the citrate precursor technique

A. Verma

a

*, O.P. Thakur

b

, C. Prakash

b

, T.C. Goel

c

, R.G. Mendiratta

d

a Department of Physics, Indian Institute of Technology, Hauz Khas, New Delhi 110016, India

b Solid State Physics Laboratory, Lucknow Road, Delhi 110054, India

c Birla Institute of Science and Technology, Goa Campus, Zuari Nagar 403 726, Goa, India

d Netaji Subhas Institute of Technology, Dwarka, New Delhi 110045, India Received 9 January 2004; received in revised form 19 July 2004; accepted 3 August 2004

Abstract

Temperature dependence of resistivity, dielectric constant and dielectric loss have been investigated for four different compositions of nickel-zinc ferrites, Nii_IZnIFe2O4 (x = 0.2, 0.35, 0.5 and 0.6), prepared by the citrate precursor technique. Activation energies calculated from the resistivity versus temperature curves for the compositions sintered at 1200 °C and 1300 °C range from 0.55 eV to 0.73 eV. Samples sintered at 1200 °C exhibit higher activation energies and low dielectric losses compared to those sintered at 1300 °C. Samples of the composition with x = 0.6 show low dielectric losses up to a measurement temperature of around 200 °C at higher frequencies as compared to samples of other compositions. The variations in activation energy with composition and sintering temperature have been explained on the basis of the site occupancy in ferrites and the atomic radii of the constituent metal ions.

Keywords: Nickel-zinc ferrites; Citrate precursor technique; Activation energy; Dielectric constant; Dielectric loss; Temperature

1. Introduction

Nickel-zinc ferrites are magnetic materials of immense technological importance with diverse applications such as low and high frequency transformer cores, antenna rods and microwave devices [1]. Performance of ferrite devices is greatly influenced by the quality of the ferrite material. Prop- erties of ferrites are found to be highly sensitive to their chem- ical composition and microstructure, which in turn are gov- erned by the preparation process. Ni-Zn ferrites prepared by the conventional ceramic method, involving a solid-state re- action between the oxides of the constituent metal ions, have been investigated extensively [2,3]. In the recent past, non- conventional wet-chemical methods have been found to have

distinct advantages over the conventional dry process [4,5].

Currently, a novel wet-chemical method known as the citrate precursor method has been gaining prominence for the prepa- ration of ferrites [6-9]. Preparation of Ni-Zn ferrites by the citrate precursor method has also been reported by the au- thors [10,11]. It has been established that nickel-zinc ferrites prepared by the citrate process posses high resistivity, which is a pre-requisite for ferrites operating at high frequencies to curb the eddy current losses. The work reported by the au- thors was confined to only room temperature studies. A need exists to study the properties as a function of temperature as well, to investigate the resistivity mechanisms and polariza- tion with temperature and also to estimate the safe operating temperature limit for the ferrite devices. In the present work, therefore, four different compositions of nickel-zinc ferrites have been prepared by the citrate precursor technique and their electrical properties are studied from room temperature to225°C.

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2. Experimental

Nickel-zinc ferrites of composition Nii_xZnxFe2O4 with x = 0.2, 0.35, 0.5 and 0.6 have been prepared. The chemicals used were iron(III) citrate (>98%, Merck, Germany), nickel nitrate (97%, Merck, India), zinc nitrate (96%, Merck, India), and citric acid (99.5%, Merck, India). The chemicals were accurately weighed in stoichiometric proportion. An aque- ous solution of Fe(III) citrate was prepared in distilled water.

Nickel nitrate and zinc nitrate were separately mixed with cit- ric acid and few drops of distilled water and heated at about 40 °C for half an hour to form the metal-citrate complex.

These solutions were then added slowly to the Fe(III) cit- rate solution with constant stirring to avoid precipitation and obtain a homogeneous mixture. The brown-colored citrate mixture thus obtained was a clear solution with no precipi- tation and hence no segregation of phases and was gradually heated at40°Cona hot plate to obtain a dried solid. This solid precursor is in the form of a uniformly colored brown trans- parent glass containing the cations homogeneously mixed on an atomic scale. The solid is then decomposed at 1000 °C in air. The product of decomposition, which was a dark brown powder, when subjected to X-ray diffraction measurements on a Rigaku Geiger Flex 3 kW diffractometer revealed a cubic ferrite structure with no extra phases. This ferrite powder was pressed into pellets of 1.3 cm diameter and 0.2 cm thickness at a pressure of 10t after mixing with about 2% by weight of polyvinyl alcohol binder. These pellets were sintered in air for 1 h at 1200 °C and 1300 °C, at a heating rate of 150 °C per hour. The pellets were then polished and coated with silver on both surfaces for the electrical measurements. dc-resistivity was measured from room temperature to about 3 00 ° C by the two-probe method using a Keithley 610 electrometer with a current measuring capability down to 10~13 A, and the dielec- tric constant as a function of temperature was obtained from capacitance measurements made on a HP-4284 LCR meter in the frequency range 100 Hz-1 MHz. The corresponding loss tangent, tan δ, was also simultaneously recorded.

3. Results and discussion

The variation of dc-resistivity as a function of temperature [logρ versus 1000/T (K"1)] is found to be linear for all the Nii_xZnxFe2O4 compositions studied. The resistivities de- crease with increasing temperature, and range from 105 Q. cm to 1011 Q. cm in the temperature range 25-300 °C. A typical curve for the sample corresponding to x = 0.5 and sintered at 1300° C is shown in Fig. 1. The activation energies cal- culated from the resistivity versus temperature plots, for the samples sintered at 1200 ° C and 13 00 ° C are given in Table 1.

As canbe seen, the activation energies for samples sintered at 1200 °C are higher compared to those obtained for samples sintered at 1300 °C. The activation energies also decrease with decrease in the zinc concentration of the samples.

1.6 1.8 2.0 2.2 2.4 2.6 2.8 3.0 3.2 3.4 1000/T(K-1)

Fig. 1. Temperature variation of logarithm of dc-resistivity of Ni0.5Zn0.5Fe2O4 sintered at 1300 °C.

Conductivity in ferrites is reported [12,13] to occur as a result of electron hopping between ions of the same element existing in different valence states on equivalent lattice sites.

The stoichiometric cubic crystal lattice of ferrite contains iron ions in the trivalent state and the nickel and zinc ions in the divalent state. Occurrence of ions in more than one valence state is caused by the preparation conditions especially the sintering temperature. F e2 + ions in the lattice are created due to zinc loss during the sintering process [14]. Loss of Zn results in cation vacancies and unsaturated oxygen ions. The excess electrons on oxygen then bond with the neighboring F e3 + ions in the spinel lattice due to electrostatic interaction giving rise to F e2 + ions. The overall charge balance is restored by oxygen loss from the sample. Formation of F e2 + ions leads to deviations from ferrite stoichiometry. The number of F e2 + ions depends on the amount of Zn lost from the sample on volatilization, which in turn is dependent on the sintering temperature of the ferrite. Higher the sintering temperature, greater is the possibility of F e2 + formation. Creation of F e2 + ions gives rise to electron hopping between the Fe ions in +2 and +3 valence states.

The hopping probability depends upon the activation en- ergy, which is associated with the electrical energy barrier experienced by the electrons during hopping. One of the ex- planations for the observed increase in activation energy with

Table 1

Variation of activation energy with composition and sintering temperature of Nii_IZnIFe2O4 ferrites

Sintering temperature (°C) Activation energy (eV) 0.6

0.5

0.35

0.2

1200 1300 1200 1300 1200 1300 1200 1300

0.73 0.65 0.64 0.63 0.64 0.63 0.60 0.55

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Z_e=90°

p = a ( | - u ) G = lattice constant

u-oxygen parameter ( J HH oxygen ion £gj = metal ion ( Me)

Fig. 2. (I) and (II) are two metal-oxygen configurations at octahedral sites.

increasing x is based on the changes in ionic distances in the ferrite crystal structure. The lattice constant 'a' of the cu- bic ferrite structure calculated from the X-ray diffractograms recorded for the various ferrite compositions is found to vary with x. The radius of Zn ions (0.82 A) being larger than that of the Ni ions (0.78 A), addition of Zn at the expense of Ni in the ferrite is expected to increase the lattice constant. This is indeed observed in the present case; the values of 'a' ob- tained for x = 0.20, 0.35, 0.50 and 0.60 sintered at 1200 °C are, respectively, 8.362 A, 8.384 A, 8.387 A and 8.422 A. The increase in the value of 'a' manifests itself as increase in the inter-ionic distances in the ferrite and consequently in an in- crease in the barrier height encountered by the hopping elec- trons. The activation energy is, therefore, expected to increase with increasing value of x.

The spinel structure of ferrites consists of two interpen- etrating sub-lattices forming two types of sites where metal ions are located; the tetrahedral (A) and the octahedral (B) sites. Zinc ions exist at the A sites while Ni ions have pref- erence for the B sites and iron ions are distributed over both the sites [ 15]. It is also known that the Ni ions exist in the +2 state and that the Fe ions exist in the +3 state; a small amount of Fe2 + is also known [16] to exist. As Zn concentration in- creases with a corresponding decrease in the Ni ions, iron ions from the A sites migrate to the B sites to accommodate the increased number of Zn ions at the A sites. The proba- bility of electron hopping, which is primarily between Fe2 +

and Fe3 + states, is greater at the B sites due to the smaller distances between the metallic ions at these sites. Two differ- ent metal-oxygen configurations [17] at the octahedral sites are possible, Fig. 2. The metal ions present in these two con- figurations are the nickel and the iron ions. Ni2 + ion being bigger (radius, 0.78 A) than the Fe3 + ion (radius, 0.67 A), the bigger bond length in configuration II of Fig. 2 suggests that the nickel ions will prefer this configuration to minimize steric hindrances. Since the number of Ni2 + ions are more at configuration II than that at configuration I, the transfer of Fe ions from A sites to configuration II of the B sites as a consequence of Ni replacement by Zn (i.e., increase in x) would be more than to configuration I. Further, the activa-

tion energy required for electron hopping between Fe2 + and Fe3 + ions in configuration II would be more due to the larger Me-Me distance in this configuration as compared to that in configuration I. The observed activation energy, E, is the weighted average of the combined activation energies of the two configurations and is given by the formula

E =

+

(1)

where EI and EII are the activation energies for electron hop- ping in configurations I and II, respectively; NI and NII are the corresponding numbers of Fe3 +-Fe2 + pairs at the two configurations. Since, with increase in x, the number NII in- creases more than the increase in number N I , and the fact that EII >EI, the weighted average activation energy is ex- pected to increase with x. This has indeed been observed in the present studies (Table 1).

As already stated, increase in sintering temperature results in the conversion of Fe3 + to Fe2 + ions. This would result in a corresponding increase in the number of Fe3 +-Fe2 + hopping pairs at the B sites. The probability of conversion of Fe3 + to Fe2 + in the two configurations of Fig. 2 depends upon:

(a) the initial amount of Fe3 + present in the respective con- figurations;

(b) the distance between the oxygen and the Fe3 + ions; as discussed earlier, smaller the distance, higher the proba- bility of electron transfer from oxygen to Fe3 + as a result of Zn evaporation; and

(c) the availability of space to accommodate Fe2 + ions.

Since Ni ion has preference for configuration II, there will be more Fe3 + ions in configuration I than in configuration II. It is obvious from Fig. 2 that the average distance be- tween oxygen and Fe ions is more in configuration II than in configuration I. Further, Fe2 + being bigger than Fe3 +, its acceptability in configuration II is more than in configuration I. Whereas points (a) and (b) above would favor Fe2 + forma- tion in configuration I, point (c) would facilitate conversion of Fe3 + to Fe2 + in configuration II. From the experimental observation that E decreases with increase in sintering tem- perature, it follows from Eq. (1) that the increase in NI as a result of increase in sintering temperature is more than the increase in NII. It is, therefore, concluded that the combined effect of (a) and (b) is more than that of (c).

In addition to the above considerations, the activation en- ergy is also influenced by the grain size. Bigger grain size implies increased grain-to-grain contact area for the electron to flow, and therefore, a lower barrier height. Since the grain size is known to increase with sintering temperature [18,19], the activation energy is expected to decrease. This explains the decrease in activation energy at higher sintering temper- atures of 1300° C.

It may be pointed out that the activation energies obtained in the present work are overall higher than those (0.1-0.4 eV) normally reported in literature [20-25] for nickel-zinc fer-

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140 120

1- 0.1 kHz

2- 1 kHz ;i

25 50 75 100 125 150 175 200 225 Temperature (°C)

Fig. 3. Temperature variation of dielectric constant, s', of Ni0.4Zn0.6Fe2O4 sintered at 1200 °C.

rites prepared by the conventional dry solid-state process.

This suggests that F e2 + ions in case of ferrites processed by the citrate precursor method are present to a relatively lower extent which in turn is indicative of lower Zn loss resulting thereby inbetter stoichiometry and hence better crystal struc- ture compared to that in ferrites obtained by the conventional solid-state method.

Dielectric constant increases with increase in temperature for all samples; the increase being quite significant at lower frequencies. Typical curves corresponding to samples of the compositions x = 0.6 and 0.2 sintered at 1200 °C are shown in Figs. 3 and 4, respectively. As seen in Fig. 4, the dielec- tric constant gradually increases with temperature at first, and decreases beyond a certain temperature. This decrease, however, is not seen in Fig. 3 in the temperature range inves- tigated, although a similar trend is visible. The temperature- dependent dispersion exhibited by the samples is consistent with the Debye-type of dispersion [26], which is expressed as

1 +

(2)

400

300

-co 2 0 0

100

. 1- 0.1 kHz 2- 1 kHz 3- 10 kHz 4- 100 kHz 5- 1 MHz

°25 50 75 100 125 150 175 200 225 Temperature (°C)

Fig. 4. Temperature variation of dielectric constant, s', sintered at 1200 °C.

where e' is the dielectric constant at frequency ω; eo and

€co, the low- and high-frequency dielectric constants, respec- tively; and τ, the relaxation time. Very high values of relax- ation time at low temperatures result in a value close to €co for the dielectric constant [27]. At high temperatures, the in- creased thermal energy provided to the sample decreases the relaxation time, and consequently, the dielectric constant in- creases. At still higher temperatures, ωτ becomes very much smaller than unity and at a certain temperature a maximum value in dielectric constant equal to eo is observed. The de- crease in dielectric constant above this temperature is due to the expected decrease in eo with further increase in temper- ature [28].

The temperature-dependent behavior of dielectric con- stant can further be explained as follows. Dielectric constant in ferrites is attributed to four types of polarizations [29]: in- terfacial, dipolar, atomic and electronic. At lower frequencies at which all four types of polarizations contribute, the rapid increase in dielectric constant with temperature is mainly due to interfacial and dipolar polarizations, which are strongly temperature dependent [30]. In case of the interfacial polar- ization, which is due to the accumulation of charges at the grainboundary, an increase in polarization results as more and more charges reach the grainboundary with increase in tem- perature. Beyond a certain temperature the charges acquire adequate thermal energy to overcome the resistive barrier at the grain boundary and conduction takes place resulting in decrease in polarization. This interfacial polarization oc- curs up to frequencies of around 1 kHz, with possibly some contribution from the dipolar polarization also as the temper- ature increases. Small rise in the curve at 10 kHz shows that there is a small contribution of dipolar polarization at this frequency. The relatively insignificant variation of dielectric constant with temperature observed at higher frequencies is ascribable to atomic and electronic polarizations, which are independent of both frequency and temperature.

A shift in the dielectric maximums is observed (Figs. 3 and 4) towards higher temperatures with increase in the measuring frequency. As the frequency increases, the electrons are not able to keep pace with the fast changing field as a result of which there is decrease in polarization. Conse- quently, higher energies are required to restore polarization, which is provided by increasing the temperature. Higher the frequency, higher the temperature required and thus the di- electric maximum shifts towards higher temperatures.

The rapid increase in dielectric constant with temperature is seen to begin at a relatively higher temperature in case of samplex = 0.6 (Fig. 3) than that for the samplex = 0.2 (Fig. 4).

This observation is commensurate with the activation ener- gies observed for the two compositions (Table 1) where the activation energy of the composition with x = 0.6 is higher than that of the composition with x = 0.2. The dielectric con- stant of the sample x = 0.2 in general is greater than that of the x = 0.6 sample. High Zn content is reported [16] to increase the reactivity of the materials during sintering and this brings about greater density and structural perfection in the ferrite.

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2000

1600

1200

800

400

025 50 75 100 125 150 175 200 225

Temperature (°C)

Fig. 5. Temperature variation of dielectric constant, s', of Ni0.4Zn0. 6Fe2O4 sintered at 1300 °C.

Structural perfection would result in higher energy barriers as the probability of localized energy states arising out of struc- tural imperfections would be low [31], decreasing thereby the probability of electron hopping and consequently the po- larization. The higher energy barrier for the x = 0.6 sample is also supported by the higher activation energy of this com- position. Besides, the polarizability of the individual metal ions also contributes to the dielectric constant. The polariz- ability of metal ions depends on the number of electrons in their outer electronic shells as well as their Goldscmidt radii [27,32]. Greater the number of electrons in their outer elec- tronic shells and greater the Goldscmidt radius, greater the polarization expected. From these considerations, the polar- izability of the cations in the ferrite would be in the order F e2 + > N i2 + > Z n2 + > F e3 +. Z n2 + and F e3 + ions would not lend themselves to polarization easily on account of their sta- ble completely filled and half-filled 3-d shells, respectively.

The observed dielectric constant is the overall result of the effect of the sum of the contribution of all these factors.

Ferrites sintered at temperatures higher than 1200 °C ex- hibit higher dielectric constants as shown in Fig. 5 for the composition x = 0.6 sintered at 1300 °C. With increase in sintering temperature, the possibility of Zn loss is greater as stated earlier. Loss of zinc results in structural imperfec- tions in the ferrite reducing thereby the energy barriers due to the formation of localized energy states, which facilitate polarization. Besides, the grain size of the ferrite sintered at 1300 °C being larger than that of the ferrite sintered at 1200 °C, the resistivity of the material is lowered as discussed earlier. Dielectric constant being inversely proportional to re- sistivity [33], a decrease in resistivity would result in higher dielectric constant.

The variation of the loss angle tangent tan δ as a function of temperature at different frequencies has also been inves- tigated for all the four nickel-zinc ferrite compositions pre- pared. Just as the dielectric constant curves, the loss curves also show an increase up to a certain temperature followed by a subsequent decrease, and can be explained on lines similar to those advanced for explaining dielectric constant. Typical

7.5 fi 0 4.5 3.0 1.5 nn

1- 0.1 kHz 2- 1 kHz 3- 10 kHz 4- 100 kHz 5- 1 MHz

y

/ MH

/ / 3 •

/ /

25 50 75 100 125 150 175 200 225 Temperature (°C)

Fig. 6. Temperature variation of dielectric loss factor, tan δ, of 6Fe2O4 (sintered at 1200 °C) measured at different frequencies.

curves corresponding to compositions with x = 0.6 and 0.2 sintered at 1200 °C are shown in Figs. 6 and 7, respectively.

These curves can be understood on the basis of the Debye equation for loss [26]:

tan δ = e s - e CO) (3)

According to this equation, tan δ would increase with de- crease in relaxation time for a given frequency. Therefore, as the relaxation time decreases with increase in temperature, tan δ increases. However, with further increase in tempera- ture, tan δ shows a decline after a certain maximum value.

This behavior is typical of relaxation losses [34]. The rapid rise in the tan δ curve at still higher temperatures is attributed to the conduction losses, which increase with temperature due to increased conduction. The tan δ losses in case of sam- ple x = 0.6 are quite low up to temperatures of around 200 °C at frequencies of 100 kHz and 1 MHz. With decrease in fre- quency, the temperature range of low losses gradually de- creases. The sample x = 0.2 exhibits comparatively higher losses with well-defined peaks in the measured temperature range. The loss peaks for the composition with x = 0.6 prob-

20

16

12

°25 50 75 100 125 150 175 200 225 Temperature (°C)

Fig. 7. Temperature variation of dielectric loss factor, tan δ, of 2Fe2O4 (sintered at 1200 °C) measured at different frequencies.

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ably occur at temperatures above 200 °C except at the fre- quency 0.1 kHz in which case there is an indication of a peak at around 175 °C. Low losses exhibited by the x = 0.6 sample up to extended temperature range suggests the applicability of this material at higher frequencies in electrical circuits which experience a high temperature rise.

4. Conclusions

The activation energy and resistivity of nickel-zinc fer- rites processed by the citrate precursor technique are higher than those reported for ferrites processed by the conventional solid-state route. This reduces the eddy current losses of the ferrites, and thus, increases their utility at high frequencies.

Besides, the dielectric losses for the samples of the compo- sitionx = 0.6 being fairly low up to about 200 °C, shows that devices utilizing this composition would be able to sustain operating temperatures up to 200 °C.

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