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A New Type of Magnetic Birefringence

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A New Type of Magnetic Birefringence

(Received

$or

publicalion, BGth Decen~ber

1931 .)

The p p r gives 8n ficcoont of the experimenh on megnetio doable refrsctian in aqueous solutions of paramognelic salt#, apecislly d tba rare earths, of which preliminary aceounte ham appeared, i n

'

Nsture,' A u p t 99, 1931, page 383, and October 31, 1931. reriurn, ptasedyminm, didy miurn (mixture of neodymium and praseodymium) and srbinm d t ~ show in aqueous eolution~ a negative magnetia birefringence comparable b mqnitude with that shown by the organia liqnids. Gadolinium nit*

does not ebow an ~pprwimble birefringence. The bitefriogence i s sensibly proportionel to the sqnere of the magnetia

field.

Tba author fiils to confirm in mian ne well as in m ~ n i t u d n the resuIts reported by mias in 1910 who oIaima to haw observed mqpetic b i r ~ f r i a g e ~ in eo1ution of erbiom nitrste.

A

eolntion of ferria ahtoride made in dilute mid to prevent e formation of colloids

duo

s b o w ~ a negdve bhbireFriag-

BIIOB,

A provisionel ~ t t e m p t ie msde to apply b a p P i n ' ~ t h r p of m w a t i c birdrin~aace to the m m of cerium nittab ~ o l n tkn, aasamin~ m optics1 snieotropy for t b a

Ce'a

ion, the assamption being juatdieble i n d e w of RmyIeigb and .Oebsnlrw' erperimenttll akrvgtion that the rare-, inolnding Xernoa to whiob the Ce' 8 ion is rn neat appmoh in drnctt~rm.

ahowe e depolarisstion of tranawrnal J acatt.emt liqbt. T ~ P t h y wlt h m e ~ i r n p l i f y i o ~ ~aumptioas, givea the r i ~ b t order of rnagnitt~da lor khr

birefringence.

A panrllelbm

appeere bo axiut betwwn tln bifelrinffanoe m d the

m a g

offeot in tbm

mlutions

in that t h m mllrtiona

which

#bow th

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