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ANALYTICAL AND NONANALYTICAL STUDIES ON DEW STATIONARY PHASES

A thesis submitted to the

INDIAN INSTITUT& OF TE CIDIOLO GY IVALBI for the de gree of

DOCTOR OF PHILOSOPHY

DWI JEN KUMAR BANtarLsE

M . S c. .Te ch.

Department of Chemistry

197

7

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( 3• .Chawla ) Assistant Peof ssor Department of Chemistry Indian Institute of Tech.

New Delhi-110029 CERTIFICATE

This is to certify that the the sis entitled

" Analytical and Thermodynamic Studies on New Stationary Phases"

being submitted by Mr.Dwijen Kumar Banerjee, Senior Research Fellow of Chemistry Department, to the Indian Institute of Technology, Delhi, for the award of the D3 gree of Doctor of Philosophy in Chemistry,

Mr.Dwijen Kumar Banerjet has worked under cur guidance and supervision and has fulfilled the requirements for the submission of the the sis .

The matter embodied in this thesis has not been submitted, in part or in full, to any other university or institute for the award of any degree or diploma.

(

i-j\A,4).4212:4- ( Dr .K.L .Mallik ) Formerly Scientist

Indian Institute of Petroleum Dehradun.

At Pre sent-

Re se arch Scientist R & D Centre

Indian Oil Corporation Faridabad(Haryana)

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THIS TrEASIS IS LEDICAgED TO MY WLCV D pARE:NTS,

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CONTLNT S

CH R

Lai

INTRODUCTION

1

( a) hi stori cal 2

( b) Gas Chromatography Process 4 (c) Distribution Ideory 6 ( d) Non-analytical Application of 11

Gas Chromatography

(e ) Advantage s of GC for Non-analytical 39 Application

II aggiLLOLOBJEt CT OF TH1 WORM

(a) Anal yti cal Appli cation of 22 gas chromatography

( b) Non-analyti cal Application of 24 gas chromatography

III

XPIL RI M6 NT AL

( a) 1 xperimental work

27

( b) (i) Synthe sis of Stationay Phase s 29 ( i) Preparation of Cyanoe thylated 22

derivative s

(ii) ) Pre paration of Allyl Alcohol 33 derivative s

( c) Infrared and Nuclear Magna tic 53 Re son ance Spe ctro scopi c S tudie s

(ci

)

Cori porEA PROgglitiPtig

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CH AP R PAM

I V AN ALYTI CAL APPLICATIONS 58 ( a) E valuation of i so-alkoxy pr opioni tr Jae 60

as stationary phase

( b) E valua tion of allyl alcohol dr rivative s 69 as stationary phase

( c) FA valuation of silane de rivative s 76

as stationary phase

( d) S Studies on short columns 87 (e ) Caprolactum as stationary phase 90 ( f) Studies on retention indices 93 ( g) Studies on polarity of the 106

stationary phase

V NON ANALYTIGALaudi,Ailiva

Introduction 112

( a) Studies on squal ane as stationary 122 Phase

( b) Studies on alkoxy pro pioni tr ile s 128 as solvents

( c) Studies on allyl alcohol derivatives 143 as stationary phase

( d) Studies on silane derivatives 164 (e ) Interaction parameter and 114

mole cul ar structure

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CHAPEt R

VI

VII

FAA

DISCUSSION AND CONCLUSION 205

S C' FOR FURTIR 4%b0RK 2]7

BIBLIOGRAPHY AP ZINDECES

BRIE F BI ()DATA OF TIE AUTHOR

References

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